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3.1. Generalized heat balance over a layer volume element
In order to consider the change of the temperature inside the layer (see Fig.
3.1), a heat balance over a volume element can be made as follows:

Fig.3.1: Generalized heat balance over a layer volume element.
Input = Output + Accumulation +Reaction
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(3.1)
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with out chemical reaction
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(3.2)
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with
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(3.3)
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(3.4)
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where
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(3.5)
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(3.6)
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(3.7)
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Using the above approach and considering different pre-defined geometries, we can write:
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(3.8)
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(3.9)
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the heat balance (eq. 3.7) reads now:
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(3.10)
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The temperature profile has to be considered for all layers. In each layer the
initial temperatures at t = 0 have to be introduced. If a layer is perfectly
isolated on its left or right side, boundary condition (I, see Fig.
2.3) is derived from the symmetrical properties of the temperature profile at the wall
surface. The other boundary conditions (II, Fig. 2.3) are derived from comparison
of the heat transfers at the interface between the different layers. We have :
- Boundary (I): Symmetry axis
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(3.11)
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(if perfect insulation)
- Boundary (II): Considering the ‘left’ and ‘right’ side of one interface, we
can write at the interface between 2 layers:
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(3.12)
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